Laura Euler Bueno: In-Depth Analysis of Alcohols as Chain Transfer Agents in the High-Pressure Polymerization of..., Kartoniert / Broschiert

Klappentext

This dissertation investigates the high-pressure polymerization of ethene, focusing on the role of various alcohols in LDPE synthesis. By applying Mayo and CLD methods at 2000 bar, the study determines the transfer constants and activation energies for different alcohol classes, revealing how molecular structure and hydroxyl group positioning directly influence transfer activity. Bridging the gap between experimental data and mathematical prediction, the research validates its kinetic findings via Predici modeling. Furthermore, it introduces a novel Python-based increment system capable of accurately predicting transfer constants based on molecular functional groups.